 
data_sl97 
 
_audit_creation_method            SHELXL-97 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             ? 
_chemical_melting_point           ? 
_chemical_formula_moiety          ? 
_chemical_formula_sum 
 'Cs6 Ge3 O9' 
_chemical_formula_weight          1159.23 
 
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'Cs'  'Cs'  -0.3680   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Ge'  'Ge'   0.1547   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'O'  'O'   0.0106   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 
_symmetry_cell_setting            ? 
_symmetry_space_group_name_H-M    ? 
 
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x, y+1/2, -z+1/2' 
 '-x, -y, -z' 
 'x, -y-1/2, z-1/2' 
 
_cell_length_a                    6.9556(6) 
_cell_length_b                    14.0256(13) 
_cell_length_c                    17.4269(15) 
_cell_angle_alpha                 90.00 
_cell_angle_beta                  107.930(3) 
_cell_angle_gamma                 90.00 
_cell_volume                      1617.5(2) 
_cell_formula_units_Z             4 
_cell_measurement_temperature     293(2) 
_cell_measurement_reflns_used     ? 
_cell_measurement_theta_min       ? 
_cell_measurement_theta_max       ? 
 
_exptl_crystal_description        ? 
_exptl_crystal_colour             ? 
_exptl_crystal_size_max           ? 
_exptl_crystal_size_mid           ? 
_exptl_crystal_size_min           ? 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     4.760 
_exptl_crystal_density_method     'not measured' 
_exptl_crystal_F_000              1992 
_exptl_absorpt_coefficient_mu     18.871 
_exptl_absorpt_correction_type    ? 
_exptl_absorpt_correction_T_min   ? 
_exptl_absorpt_correction_T_max   ? 
_exptl_absorpt_process_details    ? 
 
_exptl_special_details 
; 
 ? 
; 
 
_diffrn_ambient_temperature       293(2) 
_diffrn_radiation_wavelength      0.71073 
_diffrn_radiation_type            MoK\a 
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device_type   ? 
_diffrn_measurement_method        ? 
_diffrn_detector_area_resol_mean  ? 
_diffrn_standards_number          ? 
_diffrn_standards_interval_count  ? 
_diffrn_standards_interval_time   ? 
_diffrn_standards_decay_%         ? 
_diffrn_reflns_number             9929 
_diffrn_reflns_av_R_equivalents   0.0528 
_diffrn_reflns_av_sigmaI/netI     0.0504 
_diffrn_reflns_limit_h_min        -8 
_diffrn_reflns_limit_h_max        8 
_diffrn_reflns_limit_k_min        -18 
_diffrn_reflns_limit_k_max        17 
_diffrn_reflns_limit_l_min        -22 
_diffrn_reflns_limit_l_max        12 
_diffrn_reflns_theta_min          1.90 
_diffrn_reflns_theta_max          27.50 
_reflns_number_total              3699 
_reflns_number_gt                 2853 
_reflns_threshold_expression      >2sigma(I) 
 
_computing_data_collection        ? 
_computing_cell_refinement        ? 
_computing_data_reduction         ? 
_computing_structure_solution     'SHELXS-97 (Sheldrick, 1990)' 
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 1997)' 
_computing_molecular_graphics     ? 
_computing_publication_material   ? 
 
_refine_special_details 
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
; 
 
_refine_ls_structure_factor_coef  Fsqd  
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme       calc  
_refine_ls_weighting_details 
 'calc w=1/[σ²(Fo²)+(0.0595P)²+0.0000P] where P=(Fo²+2Fc²)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     mixed 
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        ? 
_refine_ls_number_reflns          3699 
_refine_ls_number_parameters      163 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.0566 
_refine_ls_R_factor_gt            0.0409 
_refine_ls_wR_factor_ref          0.1062 
_refine_ls_wR_factor_gt           0.0997 
_refine_ls_goodness_of_fit_ref    1.014 
_refine_ls_restrained_S_all       1.014 
_refine_ls_shift/su_max           0.001 
_refine_ls_shift/su_mean          0.000 
 
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_adp_type 
 _atom_site_occupancy 
 _atom_site_symmetry_multiplicity 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_assembly 
 _atom_site_disorder_group 
Cs1 Cs 0.00356(10) 0.38540(5) 0.41562(4) 0.02012(16) Uani 1 1 d . . . 
Cs2 Cs 0.11955(10) 0.11637(5) 0.36328(4) 0.02331(17) Uani 1 1 d . . . 
Cs3 Cs 0.12580(10) 0.80561(5) 0.30562(4) 0.02239(17) Uani 1 1 d . . . 
Cs4 Cs 0.27833(10) 0.58905(5) 0.03071(4) 0.01936(16) Uani 1 1 d . . . 
Cs5 Cs 0.34268(9) 0.50969(5) 0.28045(4) 0.01842(16) Uani 1 1 d . . . 
Cs6 Cs 0.56320(11) 0.14870(6) 0.00627(4) 0.02923(19) Uani 1 1 d . . . 
Ge1 Ge 0.16820(15) 0.12475(7) 0.13394(6) 0.0139(2) Uani 1 1 d . . . 
Ge2 Ge 0.27259(15) 0.34642(7) 0.10247(6) 0.0132(2) Uani 1 1 d . . . 
Ge3 Ge 0.45910(15) 0.25275(7) 0.28225(6) 0.0130(2) Uani 1 1 d . . . 
O1 O 0.0621(11) 0.5918(5) 0.3570(5) 0.0243(17) Uani 1 1 d . . . 
O2 O 0.1072(10) 0.4354(5) 0.1095(4) 0.0167(14) Uani 1 1 d . . . 
O3 O 0.1268(11) 0.2367(5) 0.0818(4) 0.0230(16) Uani 1 1 d . . . 
O4 O 0.2817(10) 0.0487(5) 0.0834(4) 0.0188(15) Uani 1 1 d . . . 
O5 O 0.2935(11) 0.7264(5) 0.1668(4) 0.0245(17) Uani 1 1 d . . . 
O6 O 0.3118(11) 0.3013(5) 0.3357(4) 0.0218(16) Uani 1 1 d . . . 
O7 O 0.3318(11) 0.1459(5) 0.2341(4) 0.0176(15) Uani 1 1 d . . . 
O8 O 0.4012(12) 0.3642(6) 0.0339(4) 0.0279(18) Uani 1 1 d . . . 
O9 O 0.4585(10) 0.3291(5) 0.1994(4) 0.0173(14) Uani 1 1 d . . . 
 
 
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
 
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Cs1 O4 3.034(7) 2 ? 
Cs1 O5 3.079(7) 2_545 ? 
Cs1 O4 3.108(7) 4_566 ? 
Cs1 O6 3.125(7) . ? 
Cs1 O1 3.137(8) . ? 
Cs1 O3 3.244(7) 4_566 ? 
Cs1 Ge1 3.5788(13) 2 ? 
Cs1 Ge1 3.6227(12) 4_566 ? 
Cs1 Cs6 3.7538(10) 4_566 ? 
Cs1 Cs3 3.8460(9) 2_545 ? 
Cs1 Cs6 3.8839(11) 4_466 ? 
Cs1 Cs2 4.0217(10) . ? 
Cs2 O6 3.023(7) . ? 
Cs2 O8 3.028(7) 4_566 ? 
Cs2 O7 3.077(7) . ? 
Cs2 O2 3.102(7) 2_545 ? 
Cs2 O5 3.160(7) 2_545 ? 
Cs2 Ge3 3.6447(12) . ? 
Cs2 O1 3.669(8) 2_545 ? 
Cs2 Cs5 3.7271(9) 2_545 ? 
Cs2 Cs4 3.7905(10) 2_545 ? 
Cs2 Cs3 3.9406(10) 2_545 ? 
Cs2 Ge2 4.0061(12) 4_566 ? 
Cs2 Cs4 4.0062(9) 4_566 ? 
Cs3 O9 2.938(7) 2_655 ? 
Cs3 O2 3.099(7) 2 ? 
Cs3 O3 3.161(8) 2 ? 
Cs3 O5 3.192(8) . ? 
Cs3 O1 3.200(8) . ? 
Cs3 O6 3.274(7) 2 ? 
Cs3 Ge1 3.6127(13) 2 ? 
Cs3 Ge2 3.6475(13) 2 ? 
Cs3 O8 3.695(8) 2_655 ? 
Cs3 Ge3 3.7354(13) 2_655 ? 
Cs3 O7 3.777(7) 2 ? 
Cs3 Cs1 3.8460(9) 2 ? 
Cs4 O8 2.866(8) 3_665 ? 
Cs4 O2 2.992(7) . ? 
Cs4 O5 3.032(7) . ? 
Cs4 O2 3.040(6) 3_565 ? 
Cs4 O8 3.264(8) . ? 
Cs4 Ge2 3.6300(12) . ? 
Cs4 O3 3.789(7) 3_565 ? 
Cs4 Cs2 3.7905(10) 2 ? 
Cs4 Ge2 3.9261(12) 3_565 ? 
Cs4 Ge3 3.9454(11) 2_655 ? 
Cs4 Cs6 3.9493(10) 3_665 ? 
Cs4 Cs2 4.0062(9) 4_565 ? 
Cs5 O1 2.918(7) . ? 
Cs5 O4 2.990(7) 2_655 ? 
Cs5 O7 3.032(7) 2_655 ? 
Cs5 O2 3.105(7) . ? 
Cs5 O6 3.106(7) . ? 
Cs5 O9 3.124(7) . ? 
Cs5 O5 3.586(8) . ? 
Cs5 Ge1 3.6441(12) 2_655 ? 
Cs5 Ge3 3.6917(12) . ? 
Cs5 Cs2 3.7271(9) 2 ? 
Cs5 Ge2 3.7644(12) . ? 
Cs5 Ge3 3.9552(12) 2_655 ? 
Cs6 O6 3.030(7) 4_565 ? 
Cs6 O4 3.038(7) . ? 
Cs6 O1 3.048(7) 2_645 ? 
Cs6 O8 3.312(8) . ? 
Cs6 O4 3.508(7) 3_655 ? 
Cs6 Cs1 3.7538(10) 4_565 ? 
Cs6 Cs1 3.8839(11) 4_665 ? 
Cs6 Cs4 3.9493(10) 3_665 ? 
Cs6 Cs3 3.9879(10) 2_645 ? 
Cs6 Ge3 3.9918(12) 4_565 ? 
Cs6 Ge1 4.0467(13) . ? 
Cs6 Cs5 4.0678(9) 2_645 ? 
Ge1 O1 1.721(7) 2_545 ? 
Ge1 O4 1.723(7) . ? 
Ge1 O7 1.790(6) . ? 
Ge1 O3 1.792(7) . ? 
Ge1 Cs1 3.5788(13) 2_545 ? 
Ge1 Cs3 3.6127(13) 2_545 ? 
Ge1 Cs1 3.6227(12) 4_565 ? 
Ge1 Cs5 3.6441(12) 2_645 ? 
Ge1 Cs6 4.1239(12) 1_455 ? 
Ge2 O8 1.717(7) . ? 
Ge2 O2 1.726(7) . ? 
Ge2 O9 1.800(6) . ? 
Ge2 O3 1.817(7) . ? 
Ge2 Cs3 3.6475(12) 2_545 ? 
Ge2 Cs4 3.9261(12) 3_565 ? 
Ge2 Cs2 4.0061(12) 4_565 ? 
Ge2 Cs3 4.0344(12) 2_645 ? 
Ge3 O5 1.716(7) 2_645 ? 
Ge3 O6 1.723(7) . ? 
Ge3 O9 1.796(7) . ? 
Ge3 O7 1.810(7) . ? 
Ge3 Cs3 3.7354(12) 2_645 ? 
Ge3 Cs4 3.9454(11) 2_645 ? 
Ge3 Cs3 3.9510(12) 2_545 ? 
Ge3 Cs5 3.9552(12) 2_645 ? 
Ge3 Cs6 3.9918(12) 4_566 ? 
Ge3 Cs1 4.2173(12) 1_655 ? 
O1 Ge1 1.721(7) 2 ? 
O1 Cs6 3.048(7) 2_655 ? 
O1 Cs2 3.669(8) 2 ? 
O2 Cs4 3.040(6) 3_565 ? 
O2 Cs3 3.099(7) 2_545 ? 
O2 Cs2 3.102(7) 2 ? 
O3 Cs3 3.161(8) 2_545 ? 
O3 Cs1 3.244(7) 4_565 ? 
O3 Cs4 3.789(7) 3_565 ? 
O4 Cs5 2.990(7) 2_645 ? 
O4 Cs1 3.034(7) 2_545 ? 
O4 Cs1 3.108(7) 4_565 ? 
O4 Cs6 3.508(7) 3_655 ? 
O5 Ge3 1.716(7) 2_655 ? 
O5 Cs1 3.079(7) 2 ? 
O5 Cs2 3.160(7) 2 ? 
O6 Cs6 3.030(7) 4_566 ? 
O6 Cs3 3.274(7) 2_545 ? 
O7 Cs5 3.032(7) 2_645 ? 
O7 Cs3 3.777(7) 2_545 ? 
O8 Cs4 2.866(8) 3_665 ? 
O8 Cs2 3.028(7) 4_565 ? 
O8 Cs3 3.695(8) 2_645 ? 
O9 Cs3 2.938(7) 2_645 ? 
 
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
O4 Cs1 O5 101.72(19) 2 2_545 ? 
O4 Cs1 O4 89.36(18) 2 4_566 ? 
O5 Cs1 O4 142.03(19) 2_545 4_566 ? 
O4 Cs1 O6 145.83(19) 2 . ? 
O5 Cs1 O6 88.4(2) 2_545 . ? 
O4 Cs1 O6 102.57(19) 4_566 . ? 
O4 Cs1 O1 57.06(18) 2 . ? 
O5 Cs1 O1 130.69(18) 2_545 . ? 
O4 Cs1 O1 85.78(19) 4_566 . ? 
O6 Cs1 O1 91.58(19) . . ? 
O4 Cs1 O3 112.76(19) 2 4_566 ? 
O5 Cs1 O3 89.37(18) 2_545 4_566 ? 
O4 Cs1 O3 53.17(18) 4_566 4_566 ? 
O6 Cs1 O3 99.75(19) . 4_566 ? 
O1 Cs1 O3 138.82(19) . 4_566 ? 
O4 Cs1 Ge1 28.71(13) 2 2 ? 
O5 Cs1 Ge1 116.15(13) 2_545 2 ? 
O4 Cs1 Ge1 90.73(13) 4_566 2 ? 
O6 Cs1 Ge1 118.07(13) . 2 ? 
O1 Cs1 Ge1 28.74(13) . 2 ? 
O3 Cs1 Ge1 133.43(13) 4_566 2 ? 
O4 Cs1 Ge1 91.11(13) 2 4_566 ? 
O5 Cs1 Ge1 114.28(14) 2_545 4_566 ? 
O4 Cs1 Ge1 28.36(13) 4_566 4_566 ? 
O6 Cs1 Ge1 114.50(13) . 4_566 ? 
O1 Cs1 Ge1 110.35(14) . 4_566 ? 
O3 Cs1 Ge1 29.61(13) 4_566 4_566 ? 
Ge1 Cs1 Ge1 105.33(2) 2 4_566 ? 
O4 Cs1 Cs6 133.57(13) 2 4_566 ? 
O5 Cs1 Cs6 124.34(14) 2_545 4_566 ? 
O4 Cs1 Cs6 51.50(13) 4_566 4_566 ? 
O6 Cs1 Cs6 51.29(13) . 4_566 ? 
O1 Cs1 Cs6 91.89(13) . 4_566 ? 
O3 Cs1 Cs6 66.56(14) 4_566 4_566 ? 
Ge1 Cs1 Cs6 116.55(3) 2 4_566 ? 
Ge1 Cs1 Cs6 66.51(2) 4_566 4_566 ? 
O4 Cs1 Cs3 105.89(13) 2 2_545 ? 
O5 Cs1 Cs3 53.51(15) 2_545 2_545 ? 
O4 Cs1 Cs3 156.23(13) 4_566 2_545 ? 
O6 Cs1 Cs3 54.85(13) . 2_545 ? 
O1 Cs1 Cs3 87.45(14) . 2_545 ? 
O3 Cs1 Cs3 131.09(13) 4_566 2_545 ? 
Ge1 Cs1 Cs3 94.21(2) 2 2_545 ? 
Ge1 Cs1 Cs3 160.41(3) 4_566 2_545 ? 
Cs6 Cs1 Cs3 106.08(2) 4_566 2_545 ? 
O4 Cs1 Cs6 59.43(13) 2 4_466 ? 
O5 Cs1 Cs6 66.45(15) 2_545 4_466 ? 
O4 Cs1 Cs6 89.69(13) 4_566 4_466 ? 
O6 Cs1 Cs6 150.44(13) . 4_466 ? 
O1 Cs1 Cs6 116.35(14) . 4_466 ? 
O3 Cs1 Cs6 66.22(14) 4_566 4_466 ? 
Ge1 Cs1 Cs6 88.12(3) 2 4_466 ? 
Ge1 Cs1 Cs6 66.54(2) 4_566 4_466 ? 
Cs6 Cs1 Cs6 131.20(3) 4_566 4_466 ? 
Cs3 Cs1 Cs6 113.67(2) 2_545 4_466 ? 
O4 Cs1 Cs2 152.47(13) 2 . ? 
O5 Cs1 Cs2 50.75(14) 2_545 . ? 
O4 Cs1 Cs2 112.47(13) 4_566 . ? 
O6 Cs1 Cs2 48.05(13) . . ? 
O1 Cs1 Cs2 137.42(14) . . ? 
O3 Cs1 Cs2 71.99(13) 4_566 . ? 
Ge1 Cs1 Cs2 154.26(3) 2 . ? 
Ge1 Cs1 Cs2 100.41(2) 4_566 . ? 
Cs6 Cs1 Cs2 73.825(19) 4_566 . ? 
Cs3 Cs1 Cs2 60.065(17) 2_545 . ? 
Cs6 Cs1 Cs2 102.42(2) 4_466 . ? 
O6 Cs2 O8 84.0(2) . 4_566 ? 
O6 Cs2 O7 55.45(18) . . ? 
O8 Cs2 O7 113.30(19) 4_566 . ? 
O6 Cs2 O2 175.67(18) . 2_545 ? 
O8 Cs2 O2 97.42(19) 4_566 2_545 ? 
O7 Cs2 O2 127.12(18) . 2_545 ? 
O6 Cs2 O5 88.79(19) . 2_545 ? 
O8 Cs2 O5 113.5(2) 4_566 2_545 ? 
O7 Cs2 O5 115.43(19) . 2_545 ? 
O2 Cs2 O5 86.90(18) 2_545 2_545 ? 
O6 Cs2 Ge3 28.02(14) . . ? 
O8 Cs2 Ge3 91.88(15) 4_566 . ? 
O7 Cs2 Ge3 29.74(12) . . ? 
O2 Cs2 Ge3 155.45(13) 2_545 . ? 
O5 Cs2 Ge3 110.12(14) 2_545 . ? 
O6 Cs2 O1 86.63(18) . 2_545 ? 
O8 Cs2 O1 161.12(19) 4_566 2_545 ? 
O7 Cs2 O1 48.35(17) . 2_545 ? 
O2 Cs2 O1 93.18(17) 2_545 2_545 ? 
O5 Cs2 O1 82.51(18) 2_545 2_545 ? 
Ge3 Cs2 O1 72.52(11) . 2_545 ? 
O6 Cs2 Cs5 124.74(14) . 2_545 ? 
O8 Cs2 Cs5 149.27(15) 4_566 2_545 ? 
O7 Cs2 Cs5 94.08(12) . 2_545 ? 
O2 Cs2 Cs5 53.14(12) 2_545 2_545 ? 
O5 Cs2 Cs5 62.11(14) 2_545 2_545 ? 
Ge3 Cs2 Cs5 118.56(3) . 2_545 ? 
O1 Cs2 Cs5 46.46(11) 2_545 2_545 ? 
O6 Cs2 Cs4 126.10(14) . 2_545 ? 
O8 Cs2 Cs4 83.05(15) 4_566 2_545 ? 
O7 Cs2 Cs4 163.15(13) . 2_545 ? 
O2 Cs2 Cs4 50.26(13) 2_545 2_545 ? 
O5 Cs2 Cs4 50.74(14) 2_545 2_545 ? 
Ge3 Cs2 Cs4 154.07(3) . 2_545 ? 
O1 Cs2 Cs4 115.62(11) 2_545 2_545 ? 
Cs5 Cs2 Cs4 71.261(19) 2_545 2_545 ? 
O6 Cs2 Cs3 54.17(14) . 2_545 ? 
O8 Cs2 Cs3 132.33(16) 4_566 2_545 ? 
O7 Cs2 Cs3 63.74(13) . 2_545 ? 
O2 Cs2 Cs3 122.82(12) 2_545 2_545 ? 
O5 Cs2 Cs3 52.02(14) 2_545 2_545 ? 
Ge3 Cs2 Cs3 62.64(2) . 2_545 ? 
O1 Cs2 Cs3 49.57(12) 2_545 2_545 ? 
Cs5 Cs2 Cs3 71.505(19) 2_545 2_545 ? 
Cs4 Cs2 Cs3 102.64(2) 2_545 2_545 ? 
O6 Cs2 Ge2 93.71(14) . 4_566 ? 
O8 Cs2 Ge2 23.37(15) 4_566 4_566 ? 
O7 Cs2 Ge2 135.25(12) . 4_566 ? 
O2 Cs2 Ge2 86.11(12) 2_545 4_566 ? 
O5 Cs2 Ge2 92.63(14) 2_545 4_566 ? 
Ge3 Cs2 Ge2 109.78(3) . 4_566 ? 
O1 Cs2 Ge2 175.12(12) 2_545 4_566 ? 
Cs5 Cs2 Ge2 130.50(3) 2_545 4_566 ? 
Cs4 Cs2 Ge2 60.40(2) 2_545 4_566 ? 
Cs3 Cs2 Ge2 127.21(3) 2_545 4_566 ? 
O6 Cs2 Cs4 134.13(14) . 4_566 ? 
O8 Cs2 Cs4 53.10(16) 4_566 4_566 ? 
O7 Cs2 Cs4 122.89(13) . 4_566 ? 
O2 Cs2 Cs4 48.62(12) 2_545 4_566 ? 
O5 Cs2 Cs4 120.32(14) 2_545 4_566 ? 
Ge3 Cs2 Cs4 126.40(3) . 4_566 ? 
O1 Cs2 Cs4 128.55(12) 2_545 4_566 ? 
Cs5 Cs2 Cs4 100.84(2) 2_545 4_566 ? 
Cs4 Cs2 Cs4 69.589(19) 2_545 4_566 ? 
Cs3 Cs2 Cs4 170.86(2) 2_545 4_566 ? 
Ge2 Cs2 Cs4 53.88(2) 4_566 4_566 ? 
O9 Cs3 O2 127.79(19) 2_655 2 ? 
O9 Cs3 O3 142.47(18) 2_655 2 ? 
O2 Cs3 O3 53.91(19) 2 2 ? 
O9 Cs3 O5 54.79(18) 2_655 . ? 
O2 Cs3 O5 158.95(18) 2 . ? 
O3 Cs3 O5 140.06(19) 2 . ? 
O9 Cs3 O1 109.61(19) 2_655 . ? 
O2 Cs3 O1 106.21(19) 2 . ? 
O3 Cs3 O1 52.31(19) 2 . ? 
O5 Cs3 O1 90.0(2) . . ? 
O9 Cs3 O6 132.45(18) 2_655 2 ? 
O2 Cs3 O6 82.44(17) 2 2 ? 
O3 Cs3 O6 84.01(18) 2 2 ? 
O5 Cs3 O6 83.99(17) . 2 ? 
O1 Cs3 O6 90.92(18) . 2 ? 
O9 Cs3 Ge1 137.56(14) 2_655 2 ? 
O2 Cs3 Ge1 81.20(13) 2 2 ? 
O3 Cs3 Ge1 29.74(13) 2 2 ? 
O5 Cs3 Ge1 110.39(14) . 2 ? 
O1 Cs3 Ge1 28.44(13) . 2 ? 
O6 Cs3 Ge1 74.20(13) 2 2 ? 
O9 Cs3 Ge2 152.04(13) 2_655 2 ? 
O2 Cs3 Ge2 28.18(13) 2 2 ? 
O3 Cs3 Ge2 29.88(13) 2 2 ? 
O5 Cs3 Ge2 153.11(12) . 2 ? 
O1 Cs3 Ge2 80.50(13) . 2 ? 
O6 Cs3 Ge2 71.17(13) 2 2 ? 
Ge1 Cs3 Ge2 53.66(3) 2 2 ? 
O9 Cs3 O8 48.90(17) 2_655 2_655 ? 
O2 Cs3 O8 89.02(17) 2 2_655 ? 
O3 Cs3 O8 97.69(17) 2 2_655 ? 
O5 Cs3 O8 101.70(17) . 2_655 ? 
O1 Cs3 O8 99.47(18) . 2_655 ? 
O6 Cs3 O8 168.08(18) 2 2_655 ? 
Ge1 Cs3 O8 112.80(12) 2 2_655 ? 
Ge2 Cs3 O8 104.64(12) 2 2_655 ? 
O9 Cs3 Ge3 28.11(13) 2_655 2_655 ? 
O2 Cs3 Ge3 153.65(13) 2 2_655 ? 
O3 Cs3 Ge3 147.27(13) 2 2_655 ? 
O5 Cs3 Ge3 27.26(12) . 2_655 ? 
O1 Cs3 Ge3 96.87(13) . 2_655 ? 
O6 Cs3 Ge3 110.17(13) 2 2_655 ? 
Ge1 Cs3 Ge3 123.95(3) 2 2_655 ? 
Ge2 Cs3 Ge3 177.13(3) 2 2_655 ? 
O8 Cs3 Ge3 74.56(12) 2_655 2_655 ? 
O9 Cs3 O7 147.39(17) 2_655 2 ? 
O2 Cs3 O7 84.29(16) 2 2 ? 
O3 Cs3 O7 48.27(16) 2 2 ? 
O5 Cs3 O7 97.98(17) . 2 ? 
O1 Cs3 O7 46.68(16) . 2 ? 
O6 Cs3 O7 46.80(16) 2 2 ? 
Ge1 Cs3 O7 27.92(10) 2 2 ? 
Ge2 Cs3 O7 57.47(11) 2 2 ? 
O8 Cs3 O7 140.72(15) 2_655 2 ? 
Ge3 Cs3 O7 121.42(11) 2_655 2 ? 
O9 Cs3 Cs1 82.30(13) 2_655 2 ? 
O2 Cs3 Cs1 108.20(13) 2 2 ? 
O3 Cs3 Cs1 135.07(12) 2 2 ? 
O5 Cs3 Cs1 50.86(13) . 2 ? 
O1 Cs3 Cs1 122.91(14) . 2 ? 
O6 Cs3 Cs1 51.30(13) 2 2 ? 
Ge1 Cs3 Cs1 121.19(3) 2 2 ? 
Ge2 Cs3 Cs1 114.81(2) 2 2 ? 
O8 Cs3 Cs1 124.96(12) 2_655 2 ? 
Ge3 Cs3 Cs1 67.58(2) 2_655 2 ? 
O7 Cs3 Cs1 93.73(10) 2 2 ? 
O8 Cs4 O2 144.3(2) 3_665 . ? 
O8 Cs4 O5 108.5(2) 3_665 . ? 
O2 Cs4 O5 91.2(2) . . ? 
O8 Cs4 O2 108.1(2) 3_665 3_565 ? 
O2 Cs4 O2 84.87(18) . 3_565 ? 
O5 Cs4 O2 120.65(19) . 3_565 ? 
O8 Cs4 O8 89.8(2) 3_665 . ? 
O2 Cs4 O8 55.59(19) . . ? 
O5 Cs4 O8 130.89(19) . . ? 
O2 Cs4 O8 93.82(19) 3_565 . ? 
O8 Cs4 Ge2 116.26(16) 3_665 . ? 
O2 Cs4 Ge2 28.17(13) . . ? 
O5 Cs4 Ge2 109.12(15) . . ? 
O2 Cs4 Ge2 94.06(13) 3_565 . ? 
O8 Cs4 Ge2 28.20(13) . . ? 
O8 Cs4 O3 101.2(2) 3_665 3_565 ? 
O2 Cs4 O3 111.38(17) . 3_565 ? 
O5 Cs4 O3 80.57(17) . 3_565 ? 
O2 Cs4 O3 47.57(17) 3_565 3_565 ? 
O8 Cs4 O3 141.38(17) . 3_565 ? 
Ge2 Cs4 O3 134.24(12) . 3_565 ? 
O8 Cs4 Cs2 160.28(17) 3_665 2 ? 
O2 Cs4 Cs2 52.84(14) . 2 ? 
O5 Cs4 Cs2 53.80(15) . 2 ? 
O2 Cs4 Cs2 78.89(14) 3_565 2 ? 
O8 Cs4 Cs2 108.42(13) . 2 ? 
Ge2 Cs4 Cs2 80.78(2) . 2 ? 
O3 Cs4 Cs2 69.43(12) 3_565 2 ? 
O8 Cs4 Ge2 116.78(15) 3_665 3_565 ? 
O2 Cs4 Ge2 89.06(12) . 3_565 ? 
O5 Cs4 Ge2 96.24(13) . 3_565 ? 
O2 Cs4 Ge2 24.77(13) 3_565 3_565 ? 
O8 Cs4 Ge2 115.83(14) . 3_565 ? 
Ge2 Cs4 Ge2 107.91(2) . 3_565 ? 
O3 Cs4 Ge2 27.17(11) 3_565 3_565 ? 
Cs2 Cs4 Ge2 62.52(2) 2 3_565 ? 
O8 Cs4 Ge3 88.47(16) 3_665 2_655 ? 
O2 Cs4 Ge3 100.87(13) . 2_655 ? 
O5 Cs4 Ge3 24.24(14) . 2_655 ? 
O2 Cs4 Ge3 143.02(13) 3_565 2_655 ? 
O8 Cs4 Ge3 119.74(13) . 2_655 ? 
Ge2 Cs4 Ge3 108.20(3) . 2_655 ? 
O3 Cs4 Ge3 97.67(10) 3_565 2_655 ? 
Cs2 Cs4 Ge3 76.13(2) 2 2_655 ? 
Ge2 Cs4 Ge3 118.26(3) 3_565 2_655 ? 
O8 Cs4 Cs6 55.44(16) 3_665 3_665 ? 
O2 Cs4 Cs6 156.38(14) . 3_665 ? 
O5 Cs4 Cs6 65.90(15) . 3_665 ? 
O2 Cs4 Cs6 101.25(13) 3_565 3_665 ? 
O8 Cs4 Cs6 144.90(14) . 3_665 ? 
Ge2 Cs4 Cs6 164.27(3) . 3_665 ? 
O3 Cs4 Cs6 61.01(11) 3_565 3_665 ? 
Cs2 Cs4 Cs6 105.52(2) 2 3_665 ? 
Ge2 Cs4 Cs6 87.68(2) 3_565 3_665 ? 
Ge3 Cs4 Cs6 60.75(2) 2_655 3_665 ? 
O8 Cs4 Cs2 87.24(16) 3_665 4_565 ? 
O2 Cs4 Cs2 75.92(13) . 4_565 ? 
O5 Cs4 Cs2 164.16(15) . 4_565 ? 
O2 Cs4 Cs2 49.96(13) 3_565 4_565 ? 
O8 Cs4 Cs2 47.90(13) . 4_565 ? 
Ge2 Cs4 Cs2 63.06(2) . 4_565 ? 
O3 Cs4 Cs2 95.32(10) 3_565 4_565 ? 
Cs2 Cs4 Cs2 110.411(19) 2 4_565 ? 
Ge2 Cs4 Cs2 74.64(2) 3_565 4_565 ? 
Ge3 Cs4 Cs2 166.88(3) 2_655 4_565 ? 
Cs6 Cs4 Cs2 125.39(2) 3_665 4_565 ? 
O1 Cs5 O4 96.3(2) . 2_655 ? 
O1 Cs5 O7 114.3(2) . 2_655 ? 
O4 Cs5 O7 57.22(18) 2_655 2_655 ? 
O1 Cs5 O2 109.96(19) . . ? 
O4 Cs5 O2 153.76(19) 2_655 . ? 
O7 Cs5 O2 108.57(18) 2_655 . ? 
O1 Cs5 O6 96.3(2) . . ? 
O4 Cs5 O6 93.03(19) 2_655 . ? 
O7 Cs5 O6 138.05(18) 2_655 . ? 
O2 Cs5 O6 85.13(18) . . ? 
O1 Cs5 O9 145.9(2) . . ? 
O4 Cs5 O9 102.89(18) 2_655 . ? 
O7 Cs5 O9 99.81(18) 2_655 . ? 
O2 Cs5 O9 55.07(17) . . ? 
O6 Cs5 O9 55.18(18) . . ? 
O1 Cs5 O5 87.40(19) . . ? 
O4 Cs5 O5 101.24(17) 2_655 . ? 
O7 Cs5 O5 50.69(17) 2_655 . ? 
O2 Cs5 O5 79.76(17) . . ? 
O6 Cs5 O5 164.80(17) . . ? 
O9 Cs5 O5 115.58(17) . . ? 
O1 Cs5 Ge1 108.04(15) . 2_655 ? 
O4 Cs5 Ge1 27.94(14) 2_655 2_655 ? 
O7 Cs5 Ge1 29.32(12) 2_655 2_655 ? 
O2 Cs5 Ge1 133.77(13) . 2_655 ? 
O6 Cs5 Ge1 115.77(14) . 2_655 ? 
O9 Cs5 Ge1 101.89(13) . 2_655 ? 
O5 Cs5 Ge1 76.65(11) . 2_655 ? 
O1 Cs5 Ge3 123.85(15) . . ? 
O4 Cs5 Ge3 92.06(14) 2_655 . ? 
O7 Cs5 Ge3 116.64(13) 2_655 . ? 
O2 Cs5 Ge3 74.33(13) . . ? 
O6 Cs5 Ge3 27.69(13) . . ? 
O9 Cs5 Ge3 29.05(13) . . ? 
O5 Cs5 Ge3 144.63(12) . . ? 
Ge1 Cs5 Ge3 104.72(3) 2_655 . ? 
O1 Cs5 Cs2 65.72(15) . 2 ? 
O4 Cs5 Cs2 145.31(14) 2_655 2 ? 
O7 Cs5 Cs2 101.70(12) 2_655 2 ? 
O2 Cs5 Cs2 53.05(13) . 2 ? 
O6 Cs5 Cs2 117.29(14) . 2 ? 
O9 Cs5 Cs2 108.12(12) . 2 ? 
O5 Cs5 Cs2 51.15(11) . 2 ? 
Ge1 Cs5 Cs2 126.93(3) 2_655 2 ? 
Ge3 Cs5 Cs2 122.63(2) . 2 ? 
O1 Cs5 Ge2 132.94(15) . . ? 
O4 Cs5 Ge2 128.69(14) 2_655 . ? 
O7 Cs5 Ge2 103.02(13) 2_655 . ? 
O2 Cs5 Ge2 26.99(13) . . ? 
O6 Cs5 Ge2 71.29(13) . . ? 
O9 Cs5 Ge2 28.41(12) . . ? 
O5 Cs5 Ge2 95.42(12) . . ? 
Ge1 Cs5 Ge2 118.33(3) 2_655 . ? 
Ge3 Cs5 Ge2 52.09(2) . . ? 
Cs2 Cs5 Ge2 79.89(2) 2 . ? 
O1 Cs5 Ge3 97.20(15) . 2_655 ? 
O4 Cs5 Ge3 76.58(14) 2_655 2_655 ? 
O7 Cs5 Ge3 25.98(13) 2_655 2_655 ? 
O2 Cs5 Ge3 98.63(13) . 2_655 ? 
O6 Cs5 Ge3 163.77(14) . 2_655 ? 
O9 Cs5 Ge3 114.44(13) . 2_655 ? 
O5 Cs5 Ge3 25.71(11) . 2_655 ? 
Ge1 Cs5 Ge3 50.99(2) 2_655 2_655 ? 
Ge3 Cs5 Ge3 138.550(19) . 2_655 ? 
Cs2 Cs5 Ge3 76.72(2) 2 2_655 ? 
Ge2 Cs5 Ge3 105.33(3) . 2_655 ? 
O6 Cs6 O4 106.56(18) 4_565 . ? 
O6 Cs6 O1 157.5(2) 4_565 2_645 ? 
O4 Cs6 O1 92.60(19) . 2_645 ? 
O6 Cs6 O8 79.16(18) 4_565 . ? 
O4 Cs6 O8 93.59(19) . . ? 
O1 Cs6 O8 111.9(2) 2_645 . ? 
O6 Cs6 O4 84.82(17) 4_565 3_655 ? 
O4 Cs6 O4 99.26(16) . 3_655 ? 
O1 Cs6 O4 80.52(18) 2_645 3_655 ? 
O8 Cs6 O4 161.80(16) . 3_655 ? 
O6 Cs6 Cs1 53.58(14) 4_565 4_565 ? 
O4 Cs6 Cs1 53.22(13) . 4_565 ? 
O1 Cs6 Cs1 145.30(14) 2_645 4_565 ? 
O8 Cs6 Cs1 79.76(14) . 4_565 ? 
O4 Cs6 Cs1 97.66(11) 3_655 4_565 ? 
O6 Cs6 Cs1 85.35(14) 4_565 4_665 ? 
O4 Cs6 Cs1 145.03(13) . 4_665 ? 
O1 Cs6 Cs1 72.19(14) 2_645 4_665 ? 
O8 Cs6 Cs1 121.19(14) . 4_665 ? 
O4 Cs6 Cs1 48.13(12) 3_655 4_665 ? 
Cs1 Cs6 Cs1 131.20(3) 4_565 4_665 ? 
O6 Cs6 Cs4 74.34(14) 4_565 3_665 ? 
O4 Cs6 Cs4 138.82(13) . 3_665 ? 
O1 Cs6 Cs4 99.05(14) 2_645 3_665 ? 
O8 Cs6 Cs4 45.45(14) . 3_665 ? 
O4 Cs6 Cs4 121.52(12) 3_655 3_665 ? 
Cs1 Cs6 Cs4 110.82(2) 4_565 3_665 ? 
Cs1 Cs6 Cs4 75.742(19) 4_665 3_665 ? 
O6 Cs6 Cs3 132.97(14) 4_565 2_645 ? 
O4 Cs6 Cs3 98.72(13) . 2_645 ? 
O1 Cs6 Cs3 52.03(14) 2_645 2_645 ? 
O8 Cs6 Cs3 59.97(13) . 2_645 ? 
O4 Cs6 Cs3 129.66(11) 3_655 2_645 ? 
Cs1 Cs6 Cs3 130.24(3) 4_565 2_645 ? 
Cs1 Cs6 Cs3 96.10(2) 4_665 2_645 ? 
Cs4 Cs6 Cs3 60.798(17) 3_665 2_645 ? 
O6 Cs6 Ge3 23.72(14) 4_565 4_565 ? 
O4 Cs6 Ge3 130.17(13) . 4_565 ? 
O1 Cs6 Ge3 135.21(15) 2_645 4_565 ? 
O8 Cs6 Ge3 81.89(12) . 4_565 ? 
O4 Cs6 Ge3 79.97(11) 3_655 4_565 ? 
Cs1 Cs6 Ge3 77.30(2) 4_565 4_565 ? 
Cs1 Cs6 Ge3 64.74(2) 4_665 4_565 ? 
Cs4 Cs6 Ge3 59.579(19) 3_665 4_565 ? 
Cs3 Cs6 Ge3 120.13(3) 2_645 4_565 ? 
O6 Cs6 Ge1 105.90(14) 4_565 . ? 
O4 Cs6 Ge1 22.97(13) . . ? 
O1 Cs6 Ge1 96.32(14) 2_645 . ? 
O8 Cs6 Ge1 71.14(13) . . ? 
O4 Cs6 Ge1 122.23(12) 3_655 . ? 
Cs1 Cs6 Ge1 55.19(2) 4_565 . ? 
Cs1 Cs6 Ge1 165.31(3) 4_665 . ? 
Cs4 Cs6 Ge1 115.97(3) 3_665 . ? 
Cs3 Cs6 Ge1 83.23(2) 2_645 . ? 
Ge3 Cs6 Ge1 128.10(3) 4_565 . ? 
O6 Cs6 Cs5 152.76(14) 4_565 2_645 ? 
O4 Cs6 Cs5 47.06(13) . 2_645 ? 
O1 Cs6 Cs5 45.69(14) 2_645 2_645 ? 
O8 Cs6 Cs5 105.70(12) . 2_645 ? 
O4 Cs6 Cs5 92.50(11) 3_655 2_645 ? 
Cs1 Cs6 Cs5 100.24(2) 4_565 2_645 ? 
Cs1 Cs6 Cs5 112.79(2) 4_665 2_645 ? 
Cs4 Cs6 Cs5 128.39(2) 3_665 2_645 ? 
Cs3 Cs6 Cs5 67.629(18) 2_645 2_645 ? 
Ge3 Cs6 Cs5 171.61(3) 4_565 2_645 ? 
Ge1 Cs6 Cs5 53.37(2) . 2_645 ? 
O1 Ge1 O4 117.8(4) 2_545 . ? 
O1 Ge1 O7 106.6(4) 2_545 . ? 
O4 Ge1 O7 110.3(3) . . ? 
O1 Ge1 O3 105.9(4) 2_545 . ? 
O4 Ge1 O3 108.1(3) . . ? 
O7 Ge1 O3 107.7(3) . . ? 
O1 Ge1 Cs1 61.2(3) 2_545 2_545 ? 
O4 Ge1 Cs1 57.8(2) . 2_545 ? 
O7 Ge1 Cs1 117.1(2) . 2_545 ? 
O3 Ge1 Cs1 135.2(2) . 2_545 ? 
O1 Ge1 Cs3 62.3(3) 2_545 2_545 ? 
O4 Ge1 Cs3 166.9(2) . 2_545 ? 
O7 Ge1 Cs3 81.2(2) . 2_545 ? 
O3 Ge1 Cs3 61.0(3) . 2_545 ? 
Cs1 Ge1 Cs3 123.51(3) 2_545 2_545 ? 
O1 Ge1 Cs1 94.8(3) 2_545 4_565 ? 
O4 Ge1 Cs1 59.0(2) . 4_565 ? 
O7 Ge1 Cs1 158.5(2) . 4_565 ? 
O3 Ge1 Cs1 63.4(2) . 4_565 ? 
Cs1 Ge1 Cs1 74.67(2) 2_545 4_565 ? 
Cs3 Ge1 Cs1 108.03(3) 2_545 4_565 ? 
O1 Ge1 Cs5 128.4(3) 2_545 2_645 ? 
O4 Ge1 Cs5 54.4(2) . 2_645 ? 
O7 Ge1 Cs5 56.0(2) . 2_645 ? 
O3 Ge1 Cs5 125.4(3) . 2_645 ? 
Cs1 Ge1 Cs5 83.32(3) 2_545 2_645 ? 
Cs3 Ge1 Cs5 137.09(3) 2_545 2_645 ? 
Cs1 Ge1 Cs5 111.47(3) 4_565 2_645 ? 
O1 Ge1 Cs6 151.9(3) 2_545 . ? 
O4 Ge1 Cs6 43.5(2) . . ? 
O7 Ge1 Cs6 100.8(2) . . ? 
O3 Ge1 Cs6 71.3(3) . . ? 
Cs1 Ge1 Cs6 100.25(3) 2_545 . ? 
Cs3 Ge1 Cs6 130.02(3) 2_545 . ? 
Cs1 Ge1 Cs6 58.30(2) 4_565 . ? 
Cs5 Ge1 Cs6 63.61(2) 2_645 . ? 
O1 Ge1 Cs2 63.0(3) 2_545 . ? 
O4 Ge1 Cs2 131.8(2) . . ? 
O7 Ge1 Cs2 43.6(2) . . ? 
O3 Ge1 Cs2 118.0(2) . . ? 
Cs1 Ge1 Cs2 94.96(3) 2_545 . ? 
Cs3 Ge1 Cs2 60.90(2) 2_545 . ? 
Cs1 Ge1 Cs2 157.66(3) 4_565 . ? 
Cs5 Ge1 Cs2 86.29(2) 2_645 . ? 
Cs6 Ge1 Cs2 144.01(3) . . ? 
O1 Ge1 Cs6 41.2(3) 2_545 1_455 ? 
O4 Ge1 Cs6 109.1(2) . 1_455 ? 
O7 Ge1 Cs6 138.5(2) . 1_455 ? 
O3 Ge1 Cs6 71.2(2) . 1_455 ? 
Cs1 Ge1 Cs6 74.74(2) 2_545 1_455 ? 
Cs3 Ge1 Cs6 61.64(2) 2_545 1_455 ? 
Cs1 Ge1 Cs6 59.76(2) 4_565 1_455 ? 
Cs5 Ge1 Cs6 157.81(3) 2_645 1_455 ? 
Cs6 Ge1 Cs6 116.70(3) . 1_455 ? 
Cs2 Ge1 Cs6 98.68(3) . 1_455 ? 
O8 Ge2 O2 116.5(4) . . ? 
O8 Ge2 O9 107.2(3) . . ? 
O2 Ge2 O9 109.4(3) . . ? 
O8 Ge2 O3 111.3(4) . . ? 
O2 Ge2 O3 106.4(3) . . ? 
O9 Ge2 O3 105.5(3) . . ? 
O8 Ge2 Cs4 64.0(3) . . ? 
O2 Ge2 Cs4 54.9(2) . . ? 
O9 Ge2 Cs4 111.7(2) . . ? 
O3 Ge2 Cs4 142.2(2) . . ? 
O8 Ge2 Cs3 163.2(3) . 2_545 ? 
O2 Ge2 Cs3 58.0(2) . 2_545 ? 
O9 Ge2 Cs3 89.4(2) . 2_545 ? 
O3 Ge2 Cs3 60.1(3) . 2_545 ? 
Cs4 Ge2 Cs3 112.88(3) . 2_545 ? 
O8 Ge2 Cs5 121.5(3) . . ? 
O2 Ge2 Cs5 54.7(2) . . ? 
O9 Ge2 Cs5 55.6(2) . . ? 
O3 Ge2 Cs5 127.0(2) . . ? 
Cs4 Ge2 Cs5 72.62(2) . . ? 
Cs3 Ge2 Cs5 69.93(2) 2_545 . ? 
O8 Ge2 Cs4 100.3(3) . 3_565 ? 
O2 Ge2 Cs4 47.5(2) . 3_565 ? 
O9 Ge2 Cs4 151.0(2) . 3_565 ? 
O3 Ge2 Cs4 72.2(2) . 3_565 ? 
Cs4 Ge2 Cs4 72.09(2) . 3_565 ? 
Cs3 Ge2 Cs4 63.93(2) 2_545 3_565 ? 
Cs5 Ge2 Cs4 101.66(3) . 3_565 ? 
O8 Ge2 Cs2 44.4(3) . 4_565 ? 
O2 Ge2 Cs2 90.6(2) . 4_565 ? 
O9 Ge2 Cs2 151.4(2) . 4_565 ? 
O3 Ge2 Cs2 87.2(2) . 4_565 ? 
Cs4 Ge2 Cs2 63.06(2) . 4_565 ? 
Cs3 Ge2 Cs2 118.87(3) 2_545 4_565 ? 
Cs5 Ge2 Cs2 134.72(3) . 4_565 ? 
Cs4 Ge2 Cs2 57.080(19) 3_565 4_565 ? 
O8 Ge2 Cs3 66.3(3) . 2_645 ? 
O2 Ge2 Cs3 135.0(2) . 2_645 ? 
O9 Ge2 Cs3 41.5(2) . 2_645 ? 
O3 Ge2 Cs3 113.9(2) . 2_645 ? 
Cs4 Ge2 Cs3 98.61(3) . 2_645 ? 
Cs3 Ge2 Cs3 129.70(3) 2_545 2_645 ? 
Cs5 Ge2 Cs3 84.48(2) . 2_645 ? 
Cs4 Ge2 Cs3 166.33(3) 3_565 2_645 ? 
Cs2 Ge2 Cs3 110.02(3) 4_565 2_645 ? 
O8 Ge2 Cs6 51.9(3) . . ? 
O2 Ge2 Cs6 160.8(2) . . ? 
O9 Ge2 Cs6 89.4(2) . . ? 
O3 Ge2 Cs6 70.1(3) . . ? 
Cs4 Ge2 Cs6 115.84(3) . . ? 
Cs3 Ge2 Cs6 127.79(3) 2_545 . ? 
Cs5 Ge2 Cs6 142.80(3) . . ? 
Cs4 Ge2 Cs6 115.49(3) 3_565 . ? 
Cs2 Ge2 Cs6 70.60(2) 4_565 . ? 
Cs3 Ge2 Cs6 58.84(2) 2_645 . ? 
O5 Ge3 O6 118.3(4) 2_645 . ? 
O5 Ge3 O9 107.3(3) 2_645 . ? 
O6 Ge3 O9 110.2(3) . . ? 
O5 Ge3 O7 109.3(3) 2_645 . ? 
O6 Ge3 O7 106.9(3) . . ? 
O9 Ge3 O7 103.9(3) . . ? 
O5 Ge3 Cs2 110.6(3) 2_645 . ? 
O6 Ge3 Cs2 55.5(2) . . ? 
O9 Ge3 Cs2 141.5(2) . . ? 
O7 Ge3 Cs2 57.5(2) . . ? 
O5 Ge3 Cs5 113.4(3) 2_645 . ? 
O6 Ge3 Cs5 56.9(2) . . ? 
O9 Ge3 Cs5 57.7(2) . . ? 
O7 Ge3 Cs5 136.8(2) . . ? 
Cs2 Ge3 Cs5 110.43(3) . . ? 
O5 Ge3 Cs3 58.4(3) 2_645 2_645 ? 
O6 Ge3 Cs3 143.8(2) . 2_645 ? 
O9 Ge3 Cs3 50.4(2) . 2_645 ? 
O7 Ge3 Cs3 107.7(2) . 2_645 ? 
Cs2 Ge3 Cs3 159.69(4) . 2_645 ? 
Cs5 Ge3 Cs3 89.88(3) . 2_645 ? 
O5 Ge3 Cs4 46.5(3) 2_645 2_645 ? 
O6 Ge3 Cs4 89.1(2) . 2_645 ? 
O9 Ge3 Cs4 153.7(2) . 2_645 ? 
O7 Ge3 Cs4 86.4(2) . 2_645 ? 
Cs2 Ge3 Cs4 64.21(2) . 2_645 ? 
Cs5 Ge3 Cs4 128.29(3) . 2_645 ? 
Cs3 Ge3 Cs4 103.57(3) 2_645 2_645 ? 
O5 Ge3 Cs3 171.8(3) 2_645 2_545 ? 
O6 Ge3 Cs3 54.7(2) . 2_545 ? 
O9 Ge3 Cs3 80.2(2) . 2_545 ? 
O7 Ge3 Cs3 71.2(2) . 2_545 ? 
Cs2 Ge3 Cs3 62.35(2) . 2_545 ? 
Cs5 Ge3 Cs3 67.45(2) . 2_545 ? 
Cs3 Ge3 Cs3 129.60(3) 2_645 2_545 ? 
Cs4 Ge3 Cs3 126.08(3) 2_645 2_545 ? 
O5 Ge3 Cs5 65.0(3) 2_645 2_645 ? 
O6 Ge3 Cs5 143.7(2) . 2_645 ? 
O9 Ge3 Cs5 101.9(2) . 2_645 ? 
O7 Ge3 Cs5 47.2(2) . 2_645 ? 
Cs2 Ge3 Cs5 88.70(3) . 2_645 ? 
Cs5 Ge3 Cs5 158.95(3) . 2_645 ? 
Cs3 Ge3 Cs5 71.26(2) 2_645 2_645 ? 
Cs4 Ge3 Cs5 67.33(2) 2_645 2_645 ? 
Cs3 Ge3 Cs5 117.36(3) 2_545 2_645 ? 
O5 Ge3 Cs6 73.6(3) 2_645 4_566 ? 
O6 Ge3 Cs6 45.0(2) . 4_566 ? 
O9 Ge3 Cs6 122.3(2) . 4_566 ? 
O7 Ge3 Cs6 131.0(2) . 4_566 ? 
Cs2 Ge3 Cs6 75.34(2) . 4_566 ? 
Cs5 Ge3 Cs6 69.12(2) . 4_566 ? 
Cs3 Ge3 Cs6 113.69(3) 2_645 4_566 ? 
Cs4 Ge3 Cs6 59.67(2) 2_645 4_566 ? 
Cs3 Ge3 Cs6 99.74(3) 2_545 4_566 ? 
Cs5 Ge3 Cs6 126.51(3) 2_645 4_566 ? 
O5 Ge3 Cs1 39.0(3) 2_645 1_655 ? 
O6 Ge3 Cs1 96.3(2) . 1_655 ? 
O9 Ge3 Cs1 87.7(2) . 1_655 ? 
O7 Ge3 Cs1 148.1(2) . 1_655 ? 
Cs2 Ge3 Cs1 126.66(3) . 1_655 ? 
Cs5 Ge3 Cs1 74.42(2) . 1_655 ? 
Cs3 Ge3 Cs1 57.46(2) 2_645 1_655 ? 
Cs4 Ge3 Cs1 72.10(2) 2_645 1_655 ? 
Cs3 Ge3 Cs1 140.68(3) 2_545 1_655 ? 
Cs5 Ge3 Cs1 101.67(3) 2_645 1_655 ? 
Cs6 Ge3 Cs1 56.393(19) 4_566 1_655 ? 
Ge1 O1 Cs5 157.0(4) 2 . ? 
Ge1 O1 Cs6 117.0(4) 2 2_655 ? 
Cs5 O1 Cs6 85.96(19) . 2_655 ? 
Ge1 O1 Cs1 90.0(3) 2 . ? 
Cs5 O1 Cs1 87.5(2) . . ? 
Cs6 O1 Cs1 98.8(2) 2_655 . ? 
Ge1 O1 Cs3 89.2(3) 2 . ? 
Cs5 O1 Cs3 94.1(2) . . ? 
Cs6 O1 Cs3 79.30(18) 2_655 . ? 
Cs1 O1 Cs3 177.3(3) . . ? 
Ge1 O1 Cs2 92.3(3) 2 2 ? 
Cs5 O1 Cs2 67.82(16) . 2 ? 
Cs6 O1 Cs2 136.9(2) 2_655 2 ? 
Cs1 O1 Cs2 113.0(2) . 2 ? 
Cs3 O1 Cs2 69.64(15) . 2 ? 
Ge2 O2 Cs4 96.9(3) . . ? 
Ge2 O2 Cs4 107.7(3) . 3_565 ? 
Cs4 O2 Cs4 95.13(18) . 3_565 ? 
Ge2 O2 Cs3 93.9(3) . 2_545 ? 
Cs4 O2 Cs3 169.2(3) . 2_545 ? 
Cs4 O2 Cs3 81.72(16) 3_565 2_545 ? 
Ge2 O2 Cs2 169.6(3) . 2 ? 
Cs4 O2 Cs2 76.90(16) . 2 ? 
Cs4 O2 Cs2 81.42(16) 3_565 2 ? 
Cs3 O2 Cs2 92.42(19) 2_545 2 ? 
Ge2 O2 Cs5 98.3(3) . . ? 
Cs4 O2 Cs5 91.80(18) . . ? 
Cs4 O2 Cs5 152.0(3) 3_565 . ? 
Cs3 O2 Cs5 86.45(17) 2_545 . ? 
Cs2 O2 Cs5 73.81(16) 2 . ? 
Ge1 O3 Ge2 130.4(4) . . ? 
Ge1 O3 Cs3 89.2(3) . 2_545 ? 
Ge2 O3 Cs3 90.0(3) . 2_545 ? 
Ge1 O3 Cs1 87.0(2) . 4_565 ? 
Ge2 O3 Cs1 127.0(3) . 4_565 ? 
Cs3 O3 Cs1 132.1(2) 2_545 4_565 ? 
Ge1 O3 Cs4 143.6(4) . 3_565 ? 
Ge2 O3 Cs4 80.6(2) . 3_565 ? 
Cs3 O3 Cs4 69.94(15) 2_545 3_565 ? 
Cs1 O3 Cs4 85.90(15) 4_565 3_565 ? 
Ge1 O4 Cs5 97.7(3) . 2_645 ? 
Ge1 O4 Cs1 93.5(3) . 2_545 ? 
Cs5 O4 Cs1 105.7(2) 2_645 2_545 ? 
Ge1 O4 Cs6 113.5(3) . . ? 
Cs5 O4 Cs6 84.89(18) 2_645 . ? 
Cs1 O4 Cs6 149.7(3) 2_545 . ? 
Ge1 O4 Cs1 92.6(3) . 4_565 ? 
Cs5 O4 Cs1 160.0(3) 2_645 4_565 ? 
Cs1 O4 Cs1 90.64(18) 2_545 4_565 ? 
Cs6 O4 Cs1 75.28(16) . 4_565 ? 
Ge1 O4 Cs6 165.7(4) . 3_655 ? 
Cs5 O4 Cs6 84.02(16) 2_645 3_655 ? 
Cs1 O4 Cs6 72.44(15) 2_545 3_655 ? 
Cs6 O4 Cs6 80.74(16) . 3_655 ? 
Cs1 O4 Cs6 90.21(17) 4_565 3_655 ? 
Ge3 O5 Cs4 109.2(3) 2_655 . ? 
Ge3 O5 Cs1 120.5(3) 2_655 2 ? 
Cs4 O5 Cs1 103.8(2) . 2 ? 
Ge3 O5 Cs2 155.1(4) 2_655 2 ? 
Cs4 O5 Cs2 75.46(15) . 2 ? 
Cs1 O5 Cs2 80.26(17) 2 2 ? 
Ge3 O5 Cs3 94.3(3) 2_655 . ? 
Cs4 O5 Cs3 151.8(3) . . ? 
Cs1 O5 Cs3 75.64(17) 2 . ? 
Cs2 O5 Cs3 76.69(18) 2 . ? 
Ge3 O5 Cs5 89.3(3) 2_655 . ? 
Cs4 O5 Cs5 82.42(17) . . ? 
Cs1 O5 Cs5 143.9(3) 2 . ? 
Cs2 O5 Cs5 66.73(15) 2 . ? 
Cs3 O5 Cs5 82.61(18) . . ? 
Ge3 O6 Cs2 96.5(3) . . ? 
Ge3 O6 Cs6 111.2(3) . 4_566 ? 
Cs2 O6 Cs6 101.1(2) . 4_566 ? 
Ge3 O6 Cs5 95.4(3) . . ? 
Cs2 O6 Cs5 158.9(3) . . ? 
Cs6 O6 Cs5 90.69(19) 4_566 . ? 
Ge3 O6 Cs1 173.6(4) . . ? 
Cs2 O6 Cs1 81.69(18) . . ? 
Cs6 O6 Cs1 75.14(16) 4_566 . ? 
Cs5 O6 Cs1 84.56(18) . . ? 
Ge3 O6 Cs3 99.8(3) . 2_545 ? 
Cs2 O6 Cs3 77.37(17) . 2_545 ? 
Cs6 O6 Cs3 148.8(3) 4_566 2_545 ? 
Cs5 O6 Cs3 83.46(17) . 2_545 ? 
Cs1 O6 Cs3 73.84(16) . 2_545 ? 
Ge1 O7 Ge3 131.5(4) . . ? 
Ge1 O7 Cs5 94.6(3) . 2_645 ? 
Ge3 O7 Cs5 106.8(3) . 2_645 ? 
Ge1 O7 Cs2 112.7(3) . . ? 
Ge3 O7 Cs2 92.8(3) . . ? 
Cs5 O7 Cs2 121.0(2) 2_645 . ? 
Ge1 O7 Cs3 70.9(2) . 2_545 ? 
Ge3 O7 Cs3 81.9(2) . 2_545 ? 
Cs5 O7 Cs3 165.3(2) 2_645 2_545 ? 
Cs2 O7 Cs3 69.32(14) . 2_545 ? 
Ge2 O8 Cs4 160.3(4) . 3_665 ? 
Ge2 O8 Cs2 112.2(4) . 4_565 ? 
Cs4 O8 Cs2 86.54(19) 3_665 4_565 ? 
Ge2 O8 Cs4 87.8(3) . . ? 
Cs4 O8 Cs4 90.2(2) 3_665 . ? 
Cs2 O8 Cs4 79.00(18) 4_565 . ? 
Ge2 O8 Cs6 104.0(3) . . ? 
Cs4 O8 Cs6 79.11(18) 3_665 . ? 
Cs2 O8 Cs6 94.9(2) 4_565 . ? 
Cs4 O8 Cs6 168.0(3) . . ? 
Ge2 O8 Cs3 88.5(3) . 2_645 ? 
Cs4 O8 Cs3 74.29(17) 3_665 2_645 ? 
Cs2 O8 Cs3 156.8(2) 4_565 2_645 ? 
Cs4 O8 Cs3 113.3(2) . 2_645 ? 
Cs6 O8 Cs3 69.13(15) . 2_645 ? 
Ge3 O9 Ge2 131.2(4) . . ? 
Ge3 O9 Cs3 101.5(3) . 2_645 ? 
Ge2 O9 Cs3 114.6(3) . 2_645 ? 
Ge3 O9 Cs5 93.3(3) . . ? 
Ge2 O9 Cs5 96.0(3) . . ? 
Cs3 O9 Cs5 119.8(2) 2_645 . ? 
 
_diffrn_measured_fraction_theta_max    0.995 
_diffrn_reflns_theta_full              27.50 
_diffrn_measured_fraction_theta_full   0.995 
_refine_diff_density_max    2.563 
_refine_diff_density_min   -2.165 
_refine_diff_density_rms    0.408 
